Q: What consequences are expected when the voltage of reverse polarity
is applied on an aluminum electrolytic capacitor?
A: The anode foil of polar aluminum electrolytic capacitor is subjected to
chemical conversion treatment forcedly so as to have withstand voltage
corresponding to the rated voltage of capacitor, while a cathode foil
has substantially no withstand voltage because it is not subjected to
such chemical conversion treatment. However, since aluminum is an active
metal, it may react with oxygen in the air to form oxide film naturally
on the cathode foil. Owing to this film, it is said that the cathode
foil will have the withstand voltage of about 1 to 1.5 V at room
temperature. Since this film is not uniform, but unstable, and shows
dispersion partly or for each lot, no guarantee is given to the
withstand voltage of cathode. In the circuit in which polarity is
reversed, it is recommended to use a non-polarized aluminum electrolytic
capacitor.
In case when the voltage higher than the withstand voltage is
applied on the cathode foil of polar aluminum electrolytic capacitor, a
current flows to electrolyze the water content in the liquid
electrolyte. Then, oxygen generated by such electrolysis will react with
the cathode foil to form oxide film on the cathode foil surface
(chemical conversion coating of cathode foil). Owing to this reaction,
the cathode foil capacity will lower. Since the capacitor capacity is
the combination of anode and cathode foil capacities, this may lead to
the decreased capacity of capacitor and further to the increase in
tangent of loss angle (tan δ).
Moreover, owing to this reaction, gases will be generated in the
capacitor, thus leading to the internal pressure buildup. The higher
the applied voltage is and the higher the ambient temperature is, the
more the gases are generated. Depending on the applied voltage and
temperature, this may sometimes lead to the phenomena such as swelling
of rubber packing of the capacitor and sometimes to activation of safety
device or slipping out of rubber packing in the products with no safety
device. Therefore, avoid the use of capacitor in the circuit where
reverse polarity connection of capacitor or application of reverse
voltage may occur.